Dictionary Definition
dyed adj : (used of color) artificially produced;
not natural; "a bleached blonde" [syn: bleached, colored, coloured]
User Contributed Dictionary
English
Derived terms
Verb
dyed- past of dye
Extensive Definition
A dye can generally be described as a colored substance that has an
affinity
to the substrate
to which it is being applied. The dye is generally applied in an
aqueous
solution, and may require a mordant to improve the fastness
of the dye on the fiber.
Both dyes and pigments appear to be colored
because they absorb some wavelengths of light preferentially. In contrast
with a dye, a pigment
generally is insoluble, and has no affinity for the substrate. Some
dyes can be precipitated
with an inert salt to produce a lake
pigment, and based on the salt used they could be aluminum
lake, calcium lake or barium lake pigments.
Archaeological
evidence shows that, particularly in India and the
Middle
East, dyeing has been carried out for over 5000 years. The dyes
were obtained from animal, vegetable or mineral origin, with no or very
little processing. By far the greatest source of dyes has been from
the plant
kingdom, notably roots,
berries, bark, leaves and wood, but only a few have ever been
used on a commercial scale.
Organic dyes
The first human-made (synthetic) organic dye, mauveine, was discovered by William Henry Perkin in 1856. Many thousands of synthetic dyes have since been prepared.Synthetic dyes quickly replaced the traditional
natural dyes. They cost less, they offered a vast range of new
colors, and they imparted better properties upon the dyed
materials. Dyes are now classified according to how they are used
in the dyeing process.
Acid dyes are
water-soluble anionic dyes that are applied to
fibers such as silk, wool, nylon and modified acrylic
fibers using neutral to acid dyebaths. Attachment to the fiber
is attributed, at least partly, to salt formation between anionic
groups in the dyes and cationic groups in the fiber.
Acid dyes are not substantive to cellulosic
fibers. Most synthetic food colors fall in this category.
Basic dyes are water-soluble cationic dyes that are mainly
applied to acrylic
fibers, but find some use for wool and silk. Usually acetic acid
is added to the dyebath to help the uptake of the dye onto the
fiber. Basic dyes are also used in the coloration of paper.
Direct or substantive
dyeing is normally carried out in a neutral or slightly
alkaline dyebath, at or
near boiling
point, with the addition of either sodium
chloride (NaCl) or sodium
sulfate (Na2SO4). Direct dyes are used on cotton, paper, leather, wool, silk and nylon. They are also used as
pH
indicators and as biological
stains.
Mordant dyes require a mordant, which improves the
fastness of the dye against water, light and perspiration. The choice of
mordant is very important as different mordants can change the
final color significantly. Most natural dyes are mordant dyes and
there is therefore a large literature base describing dyeing
techniques. The most important mordant dyes are the synthetic
mordant dyes, or chrome dyes, used for wool; these comprise some
30% of dyes used for wool, and are especially useful for black and
navy shades. The mordant, potassium
dichromate, is applied as an after-treatment. It is important
to note that many mordants, particularly those in the heavy metal
category, can be hazardous to health and extreme care must be taken
in using them.
Vat dyes are
essentially insoluble in water and incapable of dyeing fibres
directly. However, reduction in alkaline
liquor produces the water soluble alkali metal salt of the dye, which, in this
leuco form, has an affinity for the textile fibre. Subsequent
oxidation reforms the
original insoluble dye. The color of denim is due to indigo, the
original vat dye.
Reactive
dyes utilize a chromophore attached to a
substituent that is
capable of directly reacting
with the fibre substrate. The covalent bonds that attach
reactive dye to natural fibers make them among the most permanent
of dyes. "Cold" reactive dyes, such as Procion MX,
Cibacron
F, and Drimarene K,
are very easy to use because the dye can be applied at room
temperature. Reactive dyes are by far the best choice for dyeing
cotton and other cellulose fibers at home or in
the art studio.
Disperse dyes were originally developed for the
dyeing of cellulose
acetate, and are substantially water insoluble. The dyes are
finely ground in the presence of a dispersing agent and then sold
as a paste, or spray-dried and sold as a powder. Their main use is
to dye polyester but
they can also be used to dye nylon, cellulose
triacetate, and acrylic fibres. In some cases, a dyeing
temperature of 130
°C is
required, and a pressurised dyebath is used. The very fine particle
size gives a large surface area that aids dissolution to allow
uptake by the fibre. The dyeing rate can be significantly
influenced by the choice of dispersing agent used during the
grinding.
Azo dyeing is a
technique in which an insoluble azoic dye is produced directly onto
or within the fibre. This is achieved by treating a fibre with both
diazoic and coupling components. With suitable
adjustment of dyebath conditions the two components react to
produce the required insoluble azo dye. This technique of dyeing is
unique, in that the final color is controlled by the choice of the
diazoic and coupling components.
Sulfur dyes
are two part "developed" dyes used to dye cotton with dark colors.
The initial bath imparts a yellow or pale chartreuse color. This is
aftertreated with a sulfur compound in place to produce the dark
black we are familiar with in socks for instance. Sulfur Black 1 is
the largest selling dye by volume.
Food dyes
One other class which describes the role of dyes, rather than their mode of use, is the food dye. Because food dyes are classed as food additives, they are manufactured to a higher standard than some industrial dyes. Food dyes can be direct, mordant and vat dyes, and their use is strictly controlled by legislation. Many are azoic dyes, although anthraquinone and triphenylmethane compounds are used for colors such as green and blue. Some naturally-occurring dyes are also used.Other important dyes
A number of other classes have also been established, including:- Oxidation bases, for mainly hair and fur
- Leather dyes, for leather
- Fluorescent brighteners, for textile fibres and paper
- Solvent dyes, for wood staining and producing colored lacquers, solvent inks, coloring oils, waxes.
- Carbene dyes, a recently developed method for coloring multiple substrates
Chemical classification
By the nature of their chromophore, dyes are divided into: http://stainsfile.info/StainsFile/dyes/dyes.htm- :Category:Acridine dyes, derivates of acridine
- :Category:Anthraquinone dyes, derivates of anthraquinone
- Arylmethane dyes
- :Category:Diarylmethane dyes, based on diphenyl methane
- :Category:Triarylmethane dyes, derivates of triphenyl methane
- :Category:Azo dyes, based on -N=N- azo structure
- Cyanine dyes, derivates of phthalocyanine
- Diazonium dyes, based on diazonium salts
- Nitro dyes, based on a -NO2 nitro functional group
- Nitroso dyes, based on a -N=O nitroso functional group
- Phthalocyanine dyes, derivates of phthalocyanine
- Quinone-imine dyes, derivates of quinone
- :Category:Azin
dyes
- :Category:Eurhodin dyes
- :Category:Safranin dyes, derivates of safranin
- Indamins
- :Category:Indophenol dyes, derivates of indophenol
- :Category:Oxazin dyes, derivates of oxazin
- Oxazone dyes, derivates of oxazone
- :Category:Thiazin dyes, derivates of thiazin
- :Category:Azin
dyes
- :Category:Thiazole dyes, derivates of thiazole
- Xanthene dyes, derived from xanthene
- Fluorene dyes, derivates of fluorene
- Pyronin dyes
- :Category:Fluorone
dyes, based on fluorone
- :Category:Rhodamine dyes, derivates of rhodamine
- Fluorene dyes, derivates of fluorene
See also
Notes
External links
dyed in German: Farbstoffe
dyed in Spanish: Tinte
dyed in French: Teinture
dyed in Lithuanian: Dažiklis
dyed in Dutch: Kleurstof
dyed in Japanese: 染料
dyed in Korean: 염료
dyed in Polish: Substancje barwiące
dyed in Romanian: Coloranţi
dyed in Russian: Красители
dyed in Simple English: Dye
dyed in Chinese: 染料